期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 72, 页码 9112-9115出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03292e
关键词
-
资金
- National Natural Science Foundation of China [21861019]
- Natural Science Foundation of Jiangxi Province [20202ACBL203006]
The highly practical method involves the cleavage of C-N bonds on enaminones for the formation of C-CN bonds, leading to efficient synthesis of beta-cyano enones with molecular iodine catalyst. Furthermore, oxalic acid can be employed for the selective synthesis of (Z)-beta-cyano enones.
A highly practical method for C-CN bond formation by C-N bond cleavage on enaminones leading to the efficient synthesis of beta-cyano enones is developed. The reactions take place efficiently to provide (E)-beta-cyano enones with only a molecular iodine catalyst. In addition, the additional employment of oxalic acid enables the selective synthesis of (Z)-beta-cyano enones.
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