期刊
GREEN CHEMISTRY
卷 23, 期 20, 页码 8016-8029出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc01500a
关键词
-
资金
- Strategic Environmental Research and Development Program [SERDP WP-2214]
- Office of Naval Research (ONR) through a Naval Research Enterprise Internship Program (NREIP) award
This study evaluated the estrogenic activity of nine bio-based tris/bisphenols and synthesized bio-based polycarbonates with a wide range of glass transition temperatures and high thermal stabilities. The non-estrogenic properties of some compounds coupled with the good thermal properties of the bio-based polycarbonates make them sustainable, lower toxicity alternatives for BPA-based polycarbonates.
Bisphenol A (BPA) is a versatile petrochemical used in the preparation of high volume polymers including polycarbonates and epoxy resins. Unfortunately, BPA is also an endocrine disrupter and has been banned from use in various consumer products by several regulatory agencies. To address this issue, our group evaluated the estrogenic activity of nine bio-based tris/bisphenols derived from resveratrol (1 and 2), anethole (3, 4), eugenol (5), carvacrol (6), and creosol (7-9). Compounds 5-9 were determined to be nonestrogenic, while compound 3 exhibited a response at a lower concentration than BPA, and compounds 1, 2, and 4 exhibited responses similar to BPA. Polycarbonates of the bio-based bisphenols (PC3-PC9) were then synthesized via interfacial polymerization and characterized by SEC, MALDI-MS, DSC, TGA, and UV-VIS spectroscopy. The bio-based polycarbonates exhibited M-n values up to 14 600 Da (SEC) and had a wide range of glass transition temperatures (T-g) with values up to 156 degrees C (similar to 25 degrees C higher than BPA with a similar molecular weight) depending on the monomer structure. The bio-based polycarbonates had high thermal stabilities with T-d5% values up to 383 degrees C under a nitrogen atmosphere. The non-estrogenic properties of 5-9 coupled with the good thermal properties of the derivative polycarbonates suggests that these materials are sustainable, lower toxicity alternatives for BPA-based polycarbonates.
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