4.2 Article

XUV pump-XUV probe transient absorption spectroscopy at FELs

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Measuring the frequency chirp of extreme-ultraviolet free-electron laser pulses by transient absorption spectroscopy

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Summary: High-intensity ultrashort pulses at extreme ultraviolet (XUV) and x-ray photon energies delivered by state-of-the-art free-electron lasers (FELs) are transforming the field of ultrafast spectroscopy. A technique based on fundamental nonlinear optics has been experimentally demonstrated for the direct measurement of the frequency chirp of extreme-ultraviolet free-electron laser pulses, providing in-situ information on the time-energy structure of the pulses. By utilizing a rate-equation model, the frequency chirp can be directly extracted and quantified from measured data, without relying on an additional external field.

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