期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 73, 页码 9268-9271出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03448k
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资金
- National Natural Science Foundation of China [22071164]
- Soochow University
- Guangxi University of Science and Technology [03190227, 03190228]
- Guangxi Department of Science and Technology [AD19245107]
The reaction of the carbazole ligand supported Ga(i) compound LGa(THF) (3) with 1-azido-4-(tert-butyl)benzene (ArN3) resulted in the first stable tetrazagallole LGaN4Ar2 (4) with a three-coordinate Ga atom. Reduction of 4 with elemental potassium led to the radical dimer {[K(18-c-6)](+)[4](-)}(2) featuring a strong antiferromagnetic interaction between the spin centers.
The reaction of the carbazole ligand supported Ga(i) compound LGa(THF) (3) and 1-azido-4-(tert-butyl)benzene (ArN3) afforded the first stable tetrazagallole LGaN4Ar2 (4) bearing a three-coordinate Ga atom. Reduction of 4 with elemental potassium resulted in the radical dimer {[K(18-c-6)](+)[4](-)}(2), featuring a strong antiferromagnetic interaction between the spin centers.
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