期刊
DALTON TRANSACTIONS
卷 50, 期 35, 页码 12079-12082出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt02747f
关键词
-
资金
- JSPS KAKENHI [JP17K05814, JP21J22572]
The use of alkylene-bridged bis-N-heterocyclic carbene ligands enhances the reactivity of the Pt3S2 core in a triplatinum complex. Despite the potential reaction between an Ag(i) ion and the Pt-Pt bond, steric hindrance results in coordination of one sulfide ligand to the Ag(i) ion.
Alkylene-bridged bis-N-heterocyclic carbene ligands working as strong sigma-donors enhance the reactivity of the Pt3S2 core in a triplatinum complex. Although an Ag(i) ion possibly reacts with the Pt-Pt bond, one of the sulfide ligands coordinates to an Ag(i) ion due to the steric hindrance of the ligands.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据