期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 73, 页码 9300-9302出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03620c
关键词
-
资金
- Noguchi Institute
- [19H05461]
- [19K15581]
By constructing a self-assembled photoactive Ir(iii) cage-shaped complex with anion binding pockets, efficient catalysis of visible-light-induced E-Z isomerization of an anionic styrene derivative is achieved.
A molecular host with photosensitizing centers provides photo-responsive host-guest properties based on its molecular recognition ability. Here, we construct a self-assembled photoactive Ir(iii) cage-shaped complex that contains anion binding pockets on its rim. The anion recognition ability of the complex enables efficient catalysis of the visible-light-induced E-Z isomerization of an anionic styrene derivative.
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