期刊
BATTERIES & SUPERCAPS
卷 4, 期 10, 页码 1605-1610出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/batt.202100193
关键词
dual-ion battery; durable organic electrode; permeability of organic electrode; sodium organic battery
资金
- G30 program foundation of Nagoya University
The dual-ion mobilities of Na organic batteries were investigated through in-situ XRD analysis and computational estimation, taking into account molecular alignments in the solid state. The study showed that appropriate molecular alignments in three-dimensional space can lead to high battery capacities in ionic liquids.
Dual-ion mobilities of Na organic batteries are investigated with in-situ XRD analysis and computational estimation considering molecular alignments in the solid state, signifying the interactive variations of ionic-pairs of an ionic liquid electrolyte and an antiaromatic molecule, nickel(II) norcorrole (NiNc). An appropriate cavity sphere in three-dimensional molecular alignments dispensed mobilities of dual-ion in an ionic liquid, resulting in high battery capacities, supplemented with the comparison of Mes-NiNc and Ph-NiNc molecular alignments. In-situ XRD experiment, computation, and simulation perspectives afforded prospective insertion and desertion behaviors of cations and anions.
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