期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 25, 页码 3517-3527出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700121
关键词
Decarboxylation; C-H activation; Cross-coupling; Biaryls; Oxidative Coupling
资金
- Engineering and Physical Sciences Research Council (EPSRC) [EP/L014017/2]
- EPSRC [EP/L014017/2, EP/L014017/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/L014017/1, EP/L014017/2] Funding Source: researchfish
The beginning of the 21st century has seen tremendous growth in the field of decarboxylative activation. Benzoic acid derivatives are now recognised as atom-economic alternatives to traditional cross-coupling partners, and they also benefit from being inexpensive, readily available and shelf-stable reagents. In this microreview we discuss recent developments in the coupling of benzoic acid derivatives either with an arene or with a second benzoic acid derivative, a process often termed decarboxylative oxidative cross-coupling. These procedures offer great promise for the development of highly selective and atom-economic cross-couplings.
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