期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 15, 页码 2118-2121出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201601571
关键词
Photoredox catalysis; Nickel; Cross-coupling; Radical reactions; C-C coupling
资金
- Centre National de la Recherche Scientifique (CNRS)
- Universite Pierre et Marie Curie (UPMC)
- Institut Universitaire de France (IUF)
- MSER (ASN PhD grant)
- LABEX MiChem [ANR-11-IDEX-0004-02]
- La Region Martinique (PhD grant)
- ANR NHCX [11-BS07-008]
- COST Action [CM1201]
Alkylsilicates were engaged under photoredox/nickel dual catalysis conditions with alkyl halides for the first time. The C(sp(3))-C(sp(3)) cross-coupling products were obtained in moderate yields and were accompanied by the homocoupling products of the alkyl halide derivatives. These promising findings are strongly suggestive of the high synthetic potential of the dual catalytic approach for the forging of alkyl carbon-carbon bonds.
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