期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 15, 页码 2122-2125出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201601604
关键词
Photocatalysis; Carbenoids; Cyclization; Radicals; Cyclopropane
资金
- ICIQ Foundation
- CERCA Programme (Generalitat de Catalunya)
- MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319]
- CELLEX Foundation through the CELLEX-ICIQ high-throughput experimentation platform
- ICIQ
- CELLEX Foundation
A new protocol for the catalytic cyclopropanation of alpha,beta-unsaturated carbonyl compounds with diiodomethane by means of photoredox catalysis has been successfully developed. The transformation is characterized by its mild conditions, functional-group compatibility, and excellent selectivity profile.
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