期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 8, 页码 1203-1206出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700029
关键词
Annulation; C-H activation; Heterocycles; Polycycles; Rhodium
资金
- China Scholarship Council
- Alexander von Humboldt Foundation
A protocol for the rhodium(III)-catalyzed annulation of N-methoxybenzamides with 7-oxa/azabenzonorbornadienes by C-H activation was developed. This method allowed the synthesis of polycyclic products containing an oxygen/nitrogen-bridged structure in excellent yields. The annulated products were successfully transformed into benzo[b] phenanthridinones by a ring-opening/aromatization sequence.
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