期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 74, 页码 9316-9329出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04029d
关键词
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资金
- National Natural Science Foundation of China [21971252, 21991122, 21672138]
- Key Research Program of Frontier Sciences, Chinese Academy of Sciences (CAS) [QYZDJSSWSLH049]
- Youth Innovation Promotion Association CAS [2019256]
This article reviews recent progress in the transfer of transition-metal difluorocarbenes and their reactivities, providing insights that may aid in the design of catalytic transfer of difluorocarbene for various reactions.
Although transition metal carbenes have found widespread applications and difluorocarbene has served as a versatile intermediate, it is still quite challenging to make use of transition-metal difluorocarbenes in synthetic chemistry due to their unpredictable reactivities. In this Highlight, we review recent developments in the transition-metal-catalyzed or -mediated transfer of difluorocarbene and the reactivies and conversions of transition-metal difluorocarbene complexes. We start with the M=CF2 bonding, then provide the progress in the transfer of difluorocarbene, and finally briefly discuss the conversions of M=CF2 into other metal complexes. The understanding of the interesting reactivities of M=CF2 may help design the catalytic transfer of difluorocarbene for various reactions.
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