期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 47, 页码 7040-7045出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201701450
关键词
Catalyst-free reactions; Cross-coupling; Propargylic acetates; Alkenylboronic acids; Arylboronic acids
资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- Japan Society for the Promotion of Science (JSPS) [26105752, 26248031]
- Grants-in-Aid for Scientific Research [17K14487, 26105752] Funding Source: KAKEN
A cross-coupling reaction between secondary propargylic acetates and alkenylboronic acids proceeded to give 1,4-enynes in good yields without addition of transition metal catalyst and base. This simple protocol was also applicable to arylboronic acids, which gave 3-arylated alkynes in good yields. The observed induction period suggested that the reaction of propargylic acetates and organoboronic acids was affected by the in-situ generated AcOH as a catalyst, which was confirmed by a separate experiment.
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