期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 26, 页码 3886-3895出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700440
关键词
Isomerization; Allylic compounds; Ketones; Domino reactions; Hydrogen transfer
资金
- Department of Science and Technology-Science and Engineering Research Board (DST-SERB), New Delhi [SB/S1/OC-39/2014]
- Ministry of Human Resource Development (MHRD)
Transition-metal-as well as ligand-free base-mediated domino isomerization and alkylation of allylic alcohols is presented. This protocol features the conversion of simple allylic alcohols into the corresponding ketones through isomerization in the presence of a simple base. Significantly, these in situ generated ketones subsequently undergo alkylation with styrenes as electrophiles, in a domino one-pot fashion, as an atom-and step-economical chemical process.
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