期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2017, 期 32, 页码 4773-4777出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700618
关键词
Iodine-mediated reactions; Synthetic methods; Iodine; Nitrogen heterocycles; Domino reactions; Fused-ring systems
资金
- National Natural Science Foundation of China (NSFC) [21562052, 81573294, 81373285]
- Major Project for the Innovation of Industry and Research of Guangzhou City [201508020128]
- Guizhou Provincial Department of Science and Technology [LH[2014]7554]
An efficient and practical approach to 3a-azidofuroindolines and -pyrroloindolines involving an iodine-catalyzed azidation/cyclization cascade of tryptophols and tryptamines with NaN3 was developed. Further transformation of the C3-azidated product provided a key intermediate for the total synthesis of psychotriasine.
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