4.8 Article

Mg(ii) heterodinuclear catalysts delivering carbon dioxide derived multi-block polymers

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Multidisciplinary

Heterocycle/Heteroallene Ring-Opening Copolymerization: Selective Catalysis Delivering Alternating Copolymers

Alex J. Plajer et al.

Summary: Heteroatom-containing polymers have potential as sustainable replacements for petrochemicals, offering a wide range of properties for various applications. Catalysed ring-opening copolymerisation (ROCOP) provides a route to create precise new polymer structures, leading to a renaissance in research and commercial products.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Review Polymer Science

Design and structure of catalysts: syntheses of carbon dioxide-based copolymers with cyclic anhydrides and/or cyclic esters

Jiaxin Liang et al.

Summary: CO2-based poly(ester-co-carbonate)s have gained attention for their tunable degradability and adjustable thermal and mechanical properties. Various catalysts, including zinc, cobalt, and chromium complexes, have been developed to provide well-defined polymers for this methodology. The review provides an account of the catalysts used and discusses the development direction and future perspectives of catalyst design.

POLYMER JOURNAL (2021)

Article Polymer Science

A Lewis Pair as Organocatalyst for One-Pot Synthesis of Block Copolymers from a Mixture of Epoxide, Anhydride, and CO2

Jinbo Zhang et al.

Summary: The ROCOP of epoxide/anhydride/CO2 is a promising process using CO2 as a renewable resource. However, the synthesis of block copolymers from mixed monomers through a one-pot polymerization remains a great challenge. This study successfully synthesized CO2-based block copolymers using an organocatalyst, presenting a potential direction for future research.

MACROMOLECULES (2021)

Article Polymer Science

Triethylborane-Assisted Synthesis of Random and Block Poly(estercarbonate)s through One-Pot Terpolymerization of Epoxides, CO2, and Cyclic Anhydrides

Vamshi K. Chidara et al.

Summary: Poly(ester-carbonate) copolymers were synthesized by one-pot copolymerization of epoxides with anhydrides and CO2 activated by triethylborane (TEB). The feeding ratio of anhydrides to epoxides determined the structure of the copolymers, with random and tapered ester structures observed. Terpolymerizations and block copolymerizations were compared in terms of the obtained copolymers' structures and properties.

MACROMOLECULES (2021)

Article Chemistry, Multidisciplinary

Heterodinuclear Zn(II), Mg(II) or Co(III) with Na(I) Catalysts for Carbon Dioxide and Cyclohexene Oxide Ring Opening Copolymerizations

Wouter Lindeboom et al.

Summary: A series of heterodinuclear catalysts show good performance in the ring opening copolymerization of cyclohexene oxide and carbon dioxide, indicating the importance of auxiliary ligands and metal combinations in the design of efficient catalysts for carbon dioxide copolymerizations.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Review Chemistry, Multidisciplinary

Sequence Control from Mixtures: Switchable Polymerization Catalysis and Future Materials Applications

Arron C. Deacy et al.

Summary: The article discusses an efficient and broadly applicable method for producing copolymers using switchable polymerization catalysis, which utilizes a single catalyst switched between different catalytic cycles to prepare block sequence selective copolymers from monomer mixtures. It presents the principles of this catalysis, catalyst design criteria, selectivity and structural copolymer characterization tools, as well as the properties of resulting copolymers.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Review Polymer Science

Chemoselective Polymerizations

Ning Zhu et al.

Summary: Chemoselective polymerizations present a significant challenge in advanced polymer precision synthesis, with issues such as ill-defined products and low efficiency in traditional methods. Significant progress has been made in chemoselective polymerizations through the development of novel catalysis and microflow technology.

PROGRESS IN POLYMER SCIENCE (2021)

Article Chemistry, Physical

Ortho-vanillin derived Al(iii) and Co(iii) catalyst systems for switchable catalysis using ε-decalactone, phthalic anhydride and cyclohexene oxide

Wilfred T. Diment et al.

Summary: Switchable catalysis is used to prepare block polyesters efficiently using novel aluminium(iii) and cobalt(iii) complexes with high catalytic activity and selectivity. The complexes are capable of producing high molar mass polyesters suitable for future optimization of thermal-mechanical properties and applications.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Review Polymer Science

Strategies for the synthesis of block copolymers with biodegradable polyester segments

Carlos Diaz et al.

Summary: Controlled synthesis of block copolymers through ring-opening polymerization and copolymerization reactions enables the production of new materials with tunable properties by combining polyester blocks with other oxygenated polymers. This review highlights recent advances in the synthesis of multiblock copolymers with biodegradable polyester segments.

POLYMER CHEMISTRY (2021)

Article Chemistry, Inorganic & Nuclear

Bimetallic Zinc Catalysts for Ring-Opening Copolymerization Processes

Felipe de la Cruz-Martinez et al.

INORGANIC CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides

Arron C. Deacy et al.

NATURE CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Metal-Free Approach for a One-Pot Construction of Biodegradable Block Copolymers from Epoxides, Phthalic Anhydride, and CO2

Shuxian Ye et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Chemistry, Multidisciplinary

Co(III)/Alkali-Metal(I) Heterodinuclear Catalysts for the Ring-Opening Copolymerization of CO2 and Propylene Oxide

Arron C. Deacy et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

CO2-Based Block Copolymers: Present and Future Designs

Yao-Yao Zhang et al.

TRENDS IN CHEMISTRY (2020)

Article Multidisciplinary Sciences

Easy access to oxygenated block polymers via switchable catalysis

Tim Stosser et al.

NATURE COMMUNICATIONS (2019)

Article Multidisciplinary Sciences

The technological and economic prospects for CO2 utilization and removal

Cameron Hepburn et al.

NATURE (2019)

Article Chemistry, Multidisciplinary

High-Efficiency Construction of CO2-Based Healable Thermoplastic Elastomers via a Tandem Synthetic Strategy

Guan-Wen Yang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Waste not, want not: CO2 (re)cycling into block polymers

Sumesh K. Raman et al.

CHEMICAL COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Chain transfer agents utilized in epoxide and CO2 copolymerization processes

Donald J. Darensbourg

GREEN CHEMISTRY (2019)

Review Chemistry, Multidisciplinary

Advances in the use of CO2 as a renewable feedstock for the synthesis of polymers

Bruno Grignard et al.

CHEMICAL SOCIETY REVIEWS (2019)

Review Multidisciplinary Sciences

'Switch' catalysis: from monomer mixtures to sequence-controlled block copolymers

T. Stosser et al.

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES (2018)

Article Chemistry, Multidisciplinary

Functional Polycarbonates from Carbon Dioxide and Tailored Epoxide Monomers: Degradable Materials and Their Application Potential

Markus Scharfenberg et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

Article Chemistry, Multidisciplinary

Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr-Salen Catalyst To Access ABA Block Polyesters

Tim Stoesser et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Sustainable Polyester Elastomers from Lactones: Synthesis, Properties, and Enzymatic Hydrolyzability

Guilhem X. De Hoe et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Polymer Science

Carbon dioxide-based copolymers with various architectures

Yang Li et al.

PROGRESS IN POLYMER SCIENCE (2018)

Review Chemistry, Inorganic & Nuclear

Copolymerization of carbon dioxide and epoxides by metal coordination complexes

Christopher M. Kozak et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Article Chemistry, Multidisciplinary

Switch Catalysis To Deliver Multi-Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride

Tim Stoesser et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Multidisciplinary

Catalysis as an Enabling Science for Sustainable Polymers

Xiangyi Zhang et al.

CHEMICAL REVIEWS (2018)

Article Nanoscience & Nanotechnology

A Novel Single-Ion-Conducting Polymer Electrolyte Derived from CO2-Based Multifunctional Polycarbonate

Kuirong Deng et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Article Chemistry, Multidisciplinary

Chemoselective Polymerizations from Mixtures of Epoxide, Lactone, Anhydride, and Carbon Dioxide

Charles Romain et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Polymer Science

Aliphatic Polyester Block Polymer Design

Deborah K. Schneiderman et al.

MACROMOLECULES (2016)

Article Multidisciplinary Sciences

The limits of precision monomer placement in chain growth polymerization

Guillaume Gody et al.

NATURE COMMUNICATIONS (2016)

Article Chemistry, Multidisciplinary

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates

Shyeni Paul et al.

CHEMICAL COMMUNICATIONS (2015)

Article Chemistry, Multidisciplinary

Greater than the Sum of Its Parts: A Heterodinuclear Polymerization Catalyst

Jennifer A. Garden et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Selective Polymerization Catalysis: Controlling the Metal Chain End Group to Prepare Block Copolyesters

Yunqing Zhu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Chemoselective Polymerization Control: From Mixed-Monomer Feedstock to Copolymers

Charles Romain et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Multidisciplinary

Diglycerol-Based Polyesters: Melt Polymerization with Hydrophobic Anhydrides

Deivasagayam Dakshinamoorthy et al.

CHEMSUSCHEM (2014)

Article Polymer Science

From CO2-Based Multifunctional Polycarbonates With a Controlled Number of Functional Groups to Graft Polymers

Jeannette Geschwind et al.

MACROMOLECULAR CHEMISTRY AND PHYSICS (2013)

Article Chemistry, Multidisciplinary

Pre-rate-determining selectivity in the terpolymerization of epoxides, cyclic anhydrides, and CO2: A one-step route to diblock copolymers

Ryan C. Jeske et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)