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A Li3VO4 micro/nanoscale anode with fast ion transportation for advanced lithium-ion batteries: a mini-review

期刊

JOURNAL OF MATERIALS CHEMISTRY C
卷 9, 期 42, 页码 14981-14996

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1tc03757a

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资金

  1. National Natural Science Foundation of China [51971182, 51971124, 52171217, 21203051, 21643005, 21203135]
  2. Xingliao Talent Innovation Program in Science and Technology of Liaoning Province [XLYC1802052]
  3. Science and Technology Projects of Suzhou City [SYG201938, SYG202025]
  4. Science and Technology Projects of Shanxi Province [S2022-JC-YB-0440]
  5. Australian Research Council [LP120200432]

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Li3VO4 is considered a promising anode material for lithium-ion batteries due to its special crystal structure and high theoretical capacity, but its poor electronic conductivity hinders its commercial applications. Future challenges and prospects include controllable fabrication of Li3VO4, enhancing Li+ ion diffusion efficiency, real-time measurement of storage mechanisms, and green treatments for waste liquid.
In recent years, Li3VO4 has been considered as a promising anode for advanced lithium-ion batteries due to its special crystal structure and high theoretical capacity. However, the poor electronic conductivity of the Li3VO4 material hinders its commercial applications. The mini-review highlights the microstructure, preparation, modification and possible insertion/deinsertion processes of Li3VO4. Finally, the future challenges and prospects related to its application are systematically discussed, including the controllable fabrication of Li3VO4 with the exposed certain crystal plane on a large scale, the enhancement of Li+ ion diffusion efficiency, in situ measurement technologies for exploring the real-time storage mechanism, and the green treatments for waste liquid.

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