期刊
INORGANIC CHEMISTRY FRONTIERS
卷 8, 期 21, 页码 4751-4756出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qi00964h
关键词
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资金
- National Natural Science Foundation of China [21875206, 21403187]
- Natural Science Foundation of Hebei Province [B2019203487]
- Open Project in Key Laboratory of Advanced Energy Materials Chemistry (Nankai University)
By changing the electrolyte, the storage capacity and cyclic stability of organic electrodes in sodium-ion batteries can be improved. Ionic liquid electrolytes have great potential in enhancing sodium storage behavior.
The commercialization of sodium ion batteries (SIBs) accelerated the research and development of electrode materials. Organic electrodes have less restriction on the battery system and have received increasing attention. However, how to avoid the dissolution of organic materials in traditional electrolytes is a crucial element. Based on the principle of like dissolves like, ionic liquid (IL) electrolytes could bring wide horizons due to differences in polarity. In this study, the sodium storage behavior of pillar[5]quinone (P5Q) and 0.3 M NaTFSI-PY13TFSI electrolyte with a large difference in polarity was investigated. Compared with traditional electrolytes, the record-high capacity was 258 mA h g(-1) over 500 cycles at 0.2 C, and the pseudocapacitance contribution can reach 74% at 1 mV s(-1), revealing its superb storage capacity. Therefore, IL electrolytes would vigorously promote the commercialization of organic electrodes.
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