期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 9, 期 38, 页码 22064-22071出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ta04569e
关键词
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资金
- National Natural Science Foundation of China [22090043, 21622101]
- Guangxi Natural Science Foundation [2019GXNSFGA245006]
It was found that it is difficult to replace Sr with Na in Sr2MgSi2O7, forming mixed crystalline and Na-containing glassy phases in Sr2-xNaxMgSi2O7-0.5x compositions. The ionic conduction in Sr2-xNaxMgSi2O7-0.5x could potentially arise from Na+ ions in the glassy phase, as indicated by AC impedance spectroscopy measurements.
Na-doped melilite-type silicate Sr2MgSi2O7 was reported to display high oxide ion conductivity. In this work, through multiple complementary techniques including X-ray diffraction, scanning electron microscopy, transmission electron microscopy, solid-state Si-29 and Na-23 nuclear magnetic resonance spectroscopy, and DFT calculations of defect formation energies, we found that it is hard to replace Sr with Na in Sr2MgSi2O7, and the Sr2-xNaxMgSi2O7-0.5x compositions formed mixed crystalline Sr2MgSi2O7 and Na-containing glassy phases. AC impedance spectroscopy measurements indicated that the ionic conduction in Sr2-xNaxMgSi2O7-0.5x could be from Na+ ions in the glassy phase, instead of the oxide ions.
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