期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 38-39, 页码 4420-4424出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201700677
关键词
Carboranes; B-H activation; Directing groups; Rhodium; Palladium
资金
- National Natural Science Foundation of China [107305-N11412]
- National Basic Research Program of China (973 project) [2015CB856500]
- Chinese 1000 Young Talents Plan
Rhodium- and palladium-induced B2-H activation of a derivative of the monocarba-closo-dodecaborate [CB11H12](-) afforded two new transition metal complexes of this cluster. The products were formed in high yields under mild conditions. The complexes were fully characterized by spectroscopic methods, X-ray crystallography, and computational analysis. The product from the reaction with rhodium was identified as a monomeric Rh-III complex, while B-H activation with palladium afforded a dimeric Pd-II structure. Acetate-mediated deprotonation-metalation is proposed as the mechanistic pathway.
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