期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 3, 页码 723-733出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201601191
关键词
Photochemistry; Layered compounds; Iron; Magnesium; Molybdenum
资金
- Center for advanced materials, Qatar University
Herein, we report the design and successful fabrication of new Mg/Fe layered double hydroxides (LDHs) with different Mg/Fe molar ratios (2: 1, 3: 1, and 4: 1) by a coprecipitation method. The prepared Mg/Fe (4: 1) LDH sample with high crystallinity and phase purity was further modified by intercalation with molybdate anions. The structural, morphological, optical, electrochemical, and photocatalytic properties of the prepared catalysts were subsequently examined. In comparison with that of the Mg/Fe (4: 1) LDH, the photocatalytic activity of the Mg/Fe (4: 1) material with molybdate anions intercalated in the interlayer for the degradation of methyl orange (MO) was enhanced, and the processed followed apparent first-order kinet-ics. Radical-trapping experiments demonstrated that h(+), OH. radicals, and O2-. radicals are the dominant reactive species for pollutant degradation. The highest photocatalytic activity of molybdate-intercalated LDH is attributed mainly to the combined effects of its layered structure with MgII-O-FeIII linkages and intercalated molybdate anions, which act as visible-light absorption centers towards higher wavelengths and can promote charge-carrier trapping as well as hinder the photogenerated electron-hole recombination. The time-resolved photoluminescence (TRPL) spectra demonstrated the prolonged charge separation under visible light.
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