期刊
RSC ADVANCES
卷 11, 期 46, 页码 28530-28534出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ra05405h
关键词
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资金
- JSPS Kakenhi [JP19H04661, JP20K09396, JP21K14629]
- OCU 'Think globally, act locally' Research Grant for Young Scientists 2021 through the hometown donation fund of Osaka City
- Uehara Memorial Foundation
- Japan Science Society
Selective oxidation of alcohol-d(1) to prepare aldehyde-d(1) was developed using NaBD4 reduction/activated MnO2 oxidation. Various aldehyde-d(1) derivatives can be prepared with high deuterium incorporation ratio (up to 98% D) under mild conditions, tolerating halogens, alkene, alkyne, ester, nitro, and cyano groups in the substrates.
The selective oxidation of alcohol-d(1) to prepare aldehyde-d(1) was newly developed by means of NaBD4 reduction/activated MnO2 oxidation. Various aldehyde-d(1) derivatives including aromatic and unsaturated aldehyde-d(1) can be prepared with a high deuterium incorporation ratio (up to 98% D). Halogens (chloride, bromide, and iodide), alkene, alkyne, ester, nitro, and cyano groups in the substrates are tolerated under the mild conditions.
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