A mixed-valent vanadium oxide cathode with ultrahigh rate capability for aqueous zinc-ion batteries

The development of high-performance cathode materials is the key to realize commercial applications of zinc-ion batteries (ZIBs). Vanadium-based materials have been used as cathode candidates for ZIBs due to their low cost and high capacity. However, the low conductivity, unstable layered structure and slow diffusion kinetics of Zn2+ are still the main problems for vanadium-based oxides. Herein, V10O24 center dot nH(2)O with a large interlayer spacing and stable structure is successfully synthesized by inducing a VO2 phase transition through a simple refluxing process. As the ZIB cathode material, V10O24 center dot nH(2)O demonstrates a high reversible capacity of 365.3 mA h g(-1) at 0.2 A g(-1), ultrahigh rate performance (127.2 mA h g(-1) even at 80 A g(-1)), and long-term cycling stability (83.2% capacity retention over 3000 cycles at 5.0 A g(-1)). The excellent electrochemical performance is attributed to the synergistic effects of the ultrathin nanoribbon structures, oxygen vacancy and water molecules, which are favorable for enhancing the electron/ion transfer kinetics and maintaining structural stability of the V10O24 center dot nH(2)O electrode in the whole cycling process. Furthermore, ex situ XRD and XPS analyses elucidate the Zn2+ storage mechanism of the V10O24 center dot nH(2)O cathode.

Automated summary

The development of high-performance cathode materials is crucial for the commercial applications of zinc-ion batteries. Vanadium-based V10O24·nH2O shows excellent electrochemical performance as a ZIB cathode, with high reversible capacity, ultrahigh rate performance, and long-term cycling stability. The synergistic effects of ultrathin nanoribbon structures, oxygen vacancy, and water molecules contribute to enhancing the electron/ion transfer kinetics and maintaining structural stability during cycling.