期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 83, 页码 10927-10930出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04695k
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资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Canadian Foundation for Innovation Project [19119]
- Sharcnet
- Compute Canada
The dioxygenation of mesoionic N-heterocyclic olefins (mNHOs) using molecular dioxygen has been reported. Depending on the presence of a vinyl proton and acidic C-H group, the mNHOs are oxidized into different products.
We report the dioxygenation of mesoionic N-heterocyclic olefins (mNHOs) using molecular dioxygen. For 1,2,3-triazole-derived mNHOs possessing a vinyl proton and at least one acidic C-H group, they are oxidized into the corresponding triazolium benzoate salts, whereas those without vinyl proton or an acidic C-H group are oxidized into triazolium oxide and ketones/aldehydes.
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