期刊
NEW JOURNAL OF CHEMISTRY
卷 45, 期 41, 页码 19294-19303出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj00685a
关键词
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资金
- Grant Agency of the Czech Republic [17-09188Y]
- Czech Academy of Sciences under Strategy AV21
- Ministry of Education, Youth and Sports of the Czech Republic (MEYS) through the project Development of the UniCRE Centre [CZ.02.1.01/0.0/0.0/16_013/0001801, LO1606, CZ.02.1.01/0.0/0.0/16_013/0001821]
Both stirring and ultrasonic pretreatment were used to activate the gel in the synthesis of two Al-rich mordenite samples. NMR spectroscopy showed that stirring resulted in a higher fraction of AlSiAl sequences in the gel compared to ultrasonic pretreatment, leading to a difference in the organization of Al atoms in the zeolite product.
Two Al-rich mordenite samples were prepared by the same synthesis procedure except for the activation of the gel for which classical stirring and ultrasonic pretreatment was used. The organization of Al atoms both in the synthesis gel and zeolite product was investigated. Although both methods of the gel activation resulted in a similar transformation of Al and Si source according to NMR spectroscopy, stirring provided a significantly higher fraction of AlSiAl sequences in the gel compared to the ultrasonic pretreatment. These sequences were transferred to the zeolite product and were more populated in the conventionally prepared mordenite. Al atoms of AlSiAl sequences face different channels and mainly behave as single Al atoms, but they can also form Al pairs or close unpaired Al atoms, observed for the first time for mordenite.
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