4.6 Article

A graphene-Mo2C heterostructure for a highly responsive broadband photodetector

期刊

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 23, 期 40, 页码 23024-23031

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cp03536c

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资金

  1. National Key Research & Development Program of China [2016YFA0201902]
  2. National Natural Science Foundation of China [62022081, 61974099, 91733302, 61605073, 61935017]
  3. Guangdong- Hong Kong-Macau Joint Laboratory [2019B121205001]
  4. Shenzhen Nanshan District Pilotage Team Program [LHTD20170006]
  5. Macau Science and Technology Development Fund (FDCT) [0098/2020/A2, 0019/2019/AGJ, FDCT-091/2017/A2, FDCT-014/2017/AMJ]
  6. University of Macau [MYRG2019-00055-IAPME]
  7. Natural Science Foundation of Guangdong Province [2021A1515010694]

向作者/读者索取更多资源

Photodetectors based on the graphene-Mo2C heterostructure exhibit high responsivity over a broad wavelength range from visible to infrared, due to enhanced light absorption and minimal resistance for photoexcited carriers in both materials.
Photodetectors based on intrinsic graphene can operate over a broad wavelength range with ultrafast response, but their responsivity is much lower than commercial silicon photodiodes. The combination of graphene with two-dimensional (2D) semiconductors may enhance the light absorption, but there is still a cutoff wavelength originating from the bandgap of semiconductors. Here, we report a highly responsive broadband photodetector based on the heterostructure of graphene and transition metal carbides (TMCs, more specifically Mo2C). The graphene-Mo2C heterostructure enhanced light absorption over a broad wavelength range from ultraviolet to infrared. In addition, there is very small resistance for photoexcited carriers in both graphene and Mo2C. Consequently, photodetectors based on the graphene-Mo2C heterostructure deliver a very high responsivity from visible to infrared telecommunication wavelengths.

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