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Radim Hrdina
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Effect of Tethered, Axial Thioether Coordination on Rhodium(II)-Catalyzed Silyl-Hydrogen Insertion
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Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and Their Application to Catalyst-Controlled C-H Functionalization
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Synthesis and Catalytic Properties of Dirhodium Paddlewheel Complexes with Tethered, Axially Coordinating Thioether Ligands
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)
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Chiral Dirhodium(II) Carboxylates: New Insights into the Effect of Ligand Stereo-Purity on Catalyst Structure and Enantioselectivity
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Highly Regio-, Diastereo-, and Enantioselective Rhodium-Catalyzed Intramolecular Cyclopropanation of (Z)-1,3-Dienyl Aryldiazoacetates
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ORGANIC LETTERS (2017)
Synthesis of Donor/Acceptor-Substituted Diazo Compounds in Flow and Their Application in Enantioselective Dirhodium-Catalyzed Cyclopropanation and C-H Functionalization
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ORGANIC LETTERS (2017)
On the Structure of Chiral Dirhodium(II) Carboxylate Catalysts: Stereoselectivity Relevance and Insights
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Rh-Catalyzed Intermolecular Reactions of alpha-Alkyl-alpha-Diazo Carbonyl Compounds with Selectivity over beta-Hydride Migration
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ACCOUNTS OF CHEMICAL RESEARCH (2016)
Chiral Dirhodium(II) Catalysts for Selective Metal Carbene Reactions
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A Mixed-Ligand Chiral Rhodium(II) Catalyst Enables the Enantioselective Total Synthesis of PiperarborenineB
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Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis
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Kinetics of Rh(II)-Catalyzed α-Diazo-β-ketoester Decomposition and Application to the [3+6+3+6] Synthesis of Macrocycles on a Large Scale and at Low Catalyst Loadings
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)
Synthesis, crystal structures and catalytic activity of tetrakis(acetato)dirhodium(II) complexes with axial picoline ligands
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INORGANICA CHIMICA ACTA (2015)
Axial Coordination Dichotomy in Dirhodium Carbenoid Catalysis: A Curious Case of Cooperative Asymmetric Dual-Catalytic Approach toward Amino Esters
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Rhodium-Catalyzed Stereoselective Amination of Thioethers with N-Mesyloxycarbamates: DMAP and Bis(DMAP)CH2Cl2 as Key Additives
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A General Method for Artificial Metalloenzyme Formation through Strain-Promoted Azide-Alkyne Cycloaddition
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Amide-Functionalized Naphthyridines on a RhII-RhII Platform: Effect of Steric Crowding, Hemilability, and Hydrogen-Bonding Interactions on the Structural Diversity and Catalytic Activity of Dirhodium(II) Complexes
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Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three-Membered Carbocycles
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CHIRALITY (2014)
Role of Sterically Demanding Chiral Dirhodium Catalysts in Site-Selective C-H Functionalization of Activated Primary C-H Bonds
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
A tripodal peptide ligand for asymmetric Rh(II) catalysis highlights unique features of on-bead catalyst development
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Designing Enzyme-like Catalysts: A Rhodium(II) Metallopeptide Case Study
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ACCOUNTS OF CHEMICAL RESEARCH (2013)
Silica-Immobilized Chiral Dirhodium(II) Catalyst for Enantioselective Carbenoid Reactions
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ORGANIC LETTERS (2013)
Synthesis, Structural Analysis, and Catalytic Properties of Tetrakis(binaphthyl or octahydrobinaphthyl phosphate) Dirhodium(II,II) Complexes
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ORGANOMETALLICS (2013)
Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex
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The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates
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Determination of orientational isomerism in rhodium(II) metallopeptides by pyrene fluorescence
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ORGANIC & BIOMOLECULAR CHEMISTRY (2012)
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Fine Tuning of Dirhodium(II) Complexes: Exploring the Axial Modification
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ACS CATALYSIS (2012)
Design and Synthesis of Chiral Heteroleptic Rhodium(II) Carboxylate Catalysts: Experimental Investigation of Halogen Bond Rigidification Effects in Asymmetric Cyclopropanation
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ACS CATALYSIS (2012)
Contrasting Reactivity of 2-Mesityl-1,8-Naphthyridine (Mes-NP) with Singly-Bonded [RhII-RhII] and [RuI-RuI] Compounds
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AUSTRALIAN JOURNAL OF CHEMISTRY (2011)
Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes
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Synthesis of the Anti-HIV Agent (-)-Hyperolactone C by Using Oxonium Ylide Formation-Rearrangement
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Insight into the Photoinduced Ligand Exchange Reaction Pathway of cis-[Rh2(μ-O2CCH3)2(CH3CN)6]2+ with a DNA Model Chelate
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Asymmetric Rh(II)-Catalyzed Cyclopropanation of Alkenes with Diacceptor Diazo Compounds: p-Methoxyphenyl Ketone as a General Stereoselectivity Controlling Group
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Kinetic and stereoselectivity effects of phosphite ligands in dirhodiunn catalysis
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Catalytic enantioselective C-H functionalization of indoles with α-diazopropionates using chiral dirhodium(II) carboxylates: asymmetric synthesis of the (+)-α-methyl-3-indolylacetic acid fragment of acremoauxin A
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TETRAHEDRON-ASYMMETRY (2011)
A Polymer-Supported Chiral Dirhodium(II) Complex: Highly Durable and Recyclable Catalyst for Asymmetric Intramolecular C-H Insertion Reactions
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)
Chiral Induction by Cinchona Alkaloids in the Rhodium(II) Catalyzed O-H Insertion Reaction
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CHEMICAL & PHARMACEUTICAL BULLETIN (2010)
Use of achiral additives to increase the stereoselectivity in Rh(II)-catalyzed cyclopropanations
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The chiral crown conformation in paddlewheel complexes
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CHEMICAL COMMUNICATIONS (2010)
A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope
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DALTON TRANSACTIONS (2010)
Dirhodium(II) Compounds with Bridging Thienylphosphines: Studies on Reversible P,C/P,S Coordination
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CHEMISTRY-A EUROPEAN JOURNAL (2009)
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Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropa nation with α-Alkyl-α-diazoesters
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Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis of cis-Cyclopropane α-Amino Acids
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)
High symmetry dirhodium(II) paddlewheel complexes as chiral catalysts
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COORDINATION CHEMISTRY REVIEWS (2008)
Diphenylglycoluril as a novel ligand architecture for dirhodium(II) carboxamidates
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INORGANICA CHIMICA ACTA (2008)
Axial coordination of NHC ligands on dirhodium(II) complexes:: Generation of a new family of catalysts
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JOURNAL OF ORGANIC CHEMISTRY (2008)
Intramolecular C-H insertion using NHC-di-rhodium(II) complexes: the influence of axial coordination
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TETRAHEDRON LETTERS (2008)
Effect of axial coordination on the electronic structure and biological activity of dirhodium(II,II) complexes
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INORGANIC CHEMISTRY (2007)
Determination of equilibrium constants and computational interaction energies for adducts of [Rh2(RCO2)4-n(PC)n] (n=0-2) with Lewis bases
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INORGANIC CHEMISTRY (2007)
Perspective on dirhodium carboxamidates as catalysts
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Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho- metalated aryl phosphines:: Catalysis in water as solvent.: Study of a (+)-nonlinear effect
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Structural and electronic trends in ortho-metalated dirhodium(II) complexes
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Oxygen binding and activation by the complexes of PY2- and TPA-appended diphenylglycoluril receptors with copper and other metals
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DALTON TRANSACTIONS (2005)
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ORGANIC LETTERS (2004)
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
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ORGANOMETALLICS (2001)
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INORGANIC CHEMISTRY (2000)
Rhodium-carbenoid-mediated intermolecular O-H insertion reactions: a dramatic additive effect. Application in the synthesis of an ascomycin derivative
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TETRAHEDRON LETTERS (2000)
Dirhodium(II) carboxylate complexes as building blocks. Synthesis and structures of square boxes with tilted walls
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (2000)
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