期刊
DALTON TRANSACTIONS
卷 50, 期 40, 页码 -出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt03143k
关键词
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资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2019R1A2C4070584]
- Science Research Center through the National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2016R1A5A1009405]
- National Research Foundation of Korea [2019R1A2C4070584] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Combining the chemistry of TEMPO with the properties of MOFs and COFs offers potential for significant advancements in catalytic applications, with improved recyclability and selectivity. This synergy is being explored as a promising approach in catalytic reactions using functional porous materials.
It is known that 2,2,6,6-tetramethylpiperidinyl-1-oxy (or TEMPO) is a stable, radical-containing molecule, which has been utilized in various areas of organic synthesis, catalysis, polymer chemistry, electrochemical reactions, and materials chemistry. Its unique stability, attributable to its structural features, and molecular tunability allows for the modification of various materials, including the heterogenization of solid materials. Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are porous and tunable because of their ligand or linker portion, and both have been extensively studied for use in catalytic applications. Therefore, synergistically combining the chemistry of TEMPO with the properties of MOFs and COFs is a natural choice and should allow for significant advancements, including improved recyclability and selectivity. This article focuses on TEMPO-bearing MOFs and COFs for use in catalytic applications. In addition, recent strategies related to the use of these functional porous materials in catalytic reactions are also discussed.
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