期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 23, 期 41, 页码 23567-23575出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cp03472c
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资金
- CONICET, Consejo Nacional de Investigaciones Cientificas y Tecnicas, Argentina [PIP11220150100107]
The study investigated the adsorption and dissociation of ethanol on Pt/beta-Mo2C for catalytic H-2 production. Results showed that Pt modifies the lattice parameters of beta-Mo2C, affecting the Mo-Mo distances and chemical state of molybdenum and carbon. The presence of Pt increased the catalytic activity of beta-Mo2C for ethanol decomposition, demonstrating a higher production of H-2 at temperatures above 530 K.
The adsorption and dissociation of ethanol on Pt/beta-Mo2C with a low noble metal loading (0.1 wt%) is studied in the context of catalytic H-2 production from alcohols. X-ray diffraction and experimental results indicate that Pt modifies the lattice parameters of beta-Mo2C. In line with this, density functional theory calculations indicate that the Mo-Mo distances are increased due to the presence of Pt. An experimental X-ray photoelectron spectroscopy study indicates that the chemical state of both molybdenum and carbon in Pt/beta-Mo2C are very different from those in the Pt-free carbide, which is also in agreement with the DFT results, which indicate that the Pt atoms generate a redistribution of charge density in their environment. Temperature programmed reaction analysis shows that at temperatures higher than 530 K, a two-fold increase in the production of H-2, CH4 and C2H6 is observed for Pt/beta-Mo2C as compared to beta-Mo2C, suggesting a higher catalytic activity for the Pt-containing carbide than for the pristine catalyst. Additionally, H-2 production from ethanol on Pt/beta-Mo2C presents a higher activation energy (0.64 eV) than that corresponding to pristine molybdenum carbide. In agreement with this experimental result, climbing image-nudged elastic band (CI-NEB) calculations indicate that the energy barrier linked to the formation of H-2 from ethanol increases with the presence of platinum. It is concluded that the low Pt loading notably modifies the catalytic pattern of molybdenum carbide, rendering it a highly active catalyst for ethanol decomposition.
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