The Functions and Applications of Fluorinated Interface Engineering in Li-Based Secondary Batteries

Li-based secondary batteries are now attracting soaring research attention as a promising energy storage system with high energy density for commercial applications. However, the high-energy systems meanwhile are causing serious concerns on safety issues due to unstable interfaces on both cathodes and anodes. To improve interphase stability upon extended cycles, surface fluorinated treatment becomes highly desirable due to its unique capability in modulating the chemistry of electrode/electrolyte interface to ensure a stable electrochemical performance. Accordingly, it is essential that a deeper understanding on the solid electrolyte interphase (SEI), especially the role of fluorine-containing components, is demanded to guide the interface design. This review begins with an introduction to the fundamental knowledge on the structure of SEI with focus on the unique physiochemical properties of fluorides. Detailed discussions are then taken on the control strategies for a reliable construction of fluoride-based interfaces, which typically includes the surface coating of metal fluorides on cathodes and exsitu/insitu fluorination on lithium, based on which the structure-performance relationship is elaborated to inspire a rational interface engineering. Finally, perspectives are provided to give insights into the possible research directions of fluorinated SEI for further development of rechargeable Li batteries.

Automated summary

This review highlights the importance of surface fluorinated treatment for improving interphase stability in Li-based secondary batteries and discusses the strategies for constructing fluoride-based interfaces. The review also delves into the structure-performance relationship of these interfaces to inspire rational interface engineering, providing insights into possible research directions for further development of rechargeable Li batteries.