4.8 Review

Progress in batch preparation of single-atom catalysts and application in sustainable synthesis of fine chemicals

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Physical

Recent advances in single-atom catalysts for CO oxidation

Haotian Zhang et al.

Summary: Single-atom catalysts (SACs) have attracted significant attention due to their high atom utilization and excellent catalytic activities. This review discusses the design principles, synthesis methods, and the influence of metal-support interactions on the activity of SACs for CO oxidation. Moreover, the CO oxidation mechanisms over SACs are evaluated and the future research directions and challenges for SAC-catalyzed CO oxidation are outlined.

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING (2022)

Article Multidisciplinary Sciences

Atomically dispersed Ir/α-MoC catalyst with high metal loading and thermal stability for water-promoted hydrogenation reaction

Siwei Li et al.

Summary: The atomically dispersed Ir/alpha-MoC catalyst with high metal loading shows remarkable activity, selectivity, and stability for quinoline hydrogenation through a water-promoted hydrogenation mechanism. The strong interaction between Ir and alpha-MoC substrate enables high dispersion of Ir on the surface, leading to high reactivity and selectivity. The synthesis of high-loading atomically dispersed catalyst is a new strategy for efficient hydrogenation reactions.

NATIONAL SCIENCE REVIEW (2022)

Article Chemistry, Physical

Single-atom Pd catalyst anchored on Zr-based metal-organic polyhedra for Suzuki-Miyaura cross coupling reactions in aqueous media

Seongsoo Kim et al.

Summary: This study successfully achieved efficient Suzuki-Miyaura cross coupling reactions in aqueous media by designing discrete cages of metal-organic polyhedra anchoring single Pd atoms. The structure showed high stability and recyclability, making it a promising candidate for single-atom catalysis applications in water.

NANO RESEARCH (2021)

Article Chemistry, Physical

Phase tuning of ZrO2 supported cobalt catalysts for hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran under mild conditions

Tianci Xiao et al.

Summary: The crystal structure of catalyst support plays a significant role in influencing its surface and electronic properties, thereby affecting catalytic activity. By preparing monoclinic, tetragonal, and mixed phase Co/ZrO2 catalysts, different hydrogenation and hydrogenolysis activities were observed in the conversion of HMF to DMF. The interaction between cobalt and t-ZrO2 resulted in higher hydrogenation activity, while the presence of acid concentration on the surface of Co/m-ZrO2 led to higher efficiency in hydrogenolysis reactions. The combination of high hydrogenation and hydrogenolysis activities in Co/Mix-ZrO2 achieved the highest yield of DMF under mild conditions.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Distance synergy of single Ag atoms doped MoS2 for hydrogen evolution electrocatalysis

Xiaoping Gao et al.

Summary: By studying the catalysis of hydrogen evolution reaction through controlling the distance between single Ag atoms doped in MoS2, it is found that the reactivity of in-plane S atoms in HER can be adjusted by controlling the distance between the Ag atoms, which helps achieve optimal HER performance.

APPLIED SURFACE SCIENCE (2021)

Review Chemistry, Multidisciplinary

Mechanochemical Synthesis of Catalytic Materials

Amol P. Amrute et al.

Summary: The mechanochemical synthesis of nanomaterials for catalytic applications is a growing research field due to its simplicity, scalability, and eco-friendliness. The distinct material properties achieved by mechanochemistry are related to their improved catalytic performance.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Applied

Green synthesized cobalt-bipyridine constructed conjugated microporous polymer: An efficient heterogeneous catalyst for cycloaddition of epoxides via CO2 fixation under ambient conditions

Xiaofeng Zhang et al.

Summary: This study developed a new method to synthesize conjugated microporous polymers with excellent CO2 capture performance, and successfully prepared a heterogeneous catalyst with a turnover frequency of up to 250 h-1 at room temperature for the reaction of coupling epoxides with CO2 to form cyclic carbonates. The research provides an efficient strategy for the conversion of carbon dioxide with industrial and economic value.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

Article Multidisciplinary Sciences

Anomalous collapses of Nares Strait ice arches leads to enhanced export of Arctic sea ice

G. W. K. Moore et al.

Summary: Ice arches at the northern and southern ends of Nares Strait, a key passage in the Arctic, are forming for shorter durations, leading to increased ice transport and accelerating the export of multi-year ice.

NATURE COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Single-Atom Catalysts: A Sustainable Pathway for the Advanced Catalytic Applications

Baljeet Singh et al.

Summary: Understanding the relationship between catalyst structure and properties is crucial for its advancement, and single-atom catalysts have shown significant improvements in activity and stability in various applications such as oxygen reduction reaction and hydrogen evolution reaction.
Review Chemistry, Multidisciplinary

Rare-Earth-Based Metal-Organic Frameworks as Multifunctional Platforms for Catalytic Conversion

Xiaomeng Shi et al.

Summary: The collaboration between rare-earth elements and metal-organic frameworks has brought new possibilities to the field of catalytic conversion, providing promising catalysts or supports for energy conversion, environmental governance, and organic synthesis. RE-MOFs as promising candidates for catalytic conversion have attracted considerable attention.
Article Chemistry, Physical

Origin of the Activity of Co-N-C Catalysts for Chemoselective Hydrogenation of Nitroarenes

Muhong Li et al.

Summary: This study reveals several unusual generalities in the hydrogenation of nitroarenes, based on experiments with four typical Co-N-C materials derived from different methodologies, showing that the single-atom species Co-N-x are the main active sites of the Co-N-C catalysts in this process.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Navigating Copper-Atom-Pair Structural Effect inside a Porous Organic Polymer Cavity for Selective Hydrogenation of Biomass-Derived 5-Hydroxymethylfurfural

Chitra Sarkar et al.

Summary: Selective hydrogenation of biomass-derived 5-hydroxymethylfurfural (5-HMF) to produce the novel difuranic polyol scaffold 2,5-dihydroxymethylfuran (DHMF) has attracted interest. The use of stable and balanced Cu-0 and Cux+ active surface species inside a catechol-based porous organic polymer (POP) nanocage led to the development of a highly efficient Cu@C-POP catalyst for S-HMF hydrogenation, surpassing other reported copper catalysts in catalytic performance.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Nanoscience & Nanotechnology

Atomically Dispersed Vanadium Sites Anchored on N-Doped Porous Carbon for the Efficient Oxidative Coupling of Amines to Imines

Qionghao Xu et al.

Summary: The study successfully prepared atomically dispersed vanadium sites coordinated by N atoms and embedded into a porous carbon network to form the V-N-C-600 catalyst through a top-down approach. This catalyst exhibited unexpectedly high catalytic activity and stability for the direct aerobic oxidation of benzylamine, showing potential for significant applications in the field.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Physical

Developing single-site Pt catalysts for the preferential oxidation of CO: A surface science and first principles-guided approach

Jilei Liu et al.

Summary: The study demonstrates that through a comprehensive approach involving surface science, DFT calculations, and catalyst synthesis, promising catalytic materials like the single-site Pt-1/CuxO catalyst for the preferential oxidation of CO can be developed.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Direct oxidation of methane to oxygenates on supported single Cu atom catalyst

Xuan Tang et al.

Summary: Cu-1/ZSM-5 single atom catalyst shows high activity and selectivity in direct CH4 oxidation, with each isolated Cu atom stabilized by four O moieties on the ZSM-5 support forming a uniform Cu-1-O-4 entity as the active site.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Efficient overall water splitting over a Mo(IV)-doped Co3O4/NC electrocatalyst

Xinran Zhao et al.

Summary: A molybdenum-doped cobalt oxide catalyst supported on nitrogen-doped carbon was developed for efficient hydrogen and oxygen evolution reactions. The optimized sample showed the lowest overpotentials and superior bifunctional catalytic activity. The Mo dopant modulated the electronic structure and increased active surface area, enhancing the water dissociation process and OER activity.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Chemistry, Multidisciplinary

A Unique Gas-Migration, Trapping, and Emitting Strategy for High-Loading Single Atomic Cd Sites for Carbon Dioxide Electroreduction

Shuguang Wang et al.

Summary: In this study, a unique gas-migration, trapping, and emitting strategy was demonstrated for building Cd-based SAC for CO2 reduction. The SAC exhibited high-loading and high efficiency in CO2 reduction process. In situ infrared spectroscopy studies and density functional theory simulations provided insights into the catalytic mechanism of the Cd-based SAC.

NANO LETTERS (2021)

Review Chemistry, Physical

Single atom catalysts by atomic diffusion strategy

Lihong Lin et al.

Summary: Energy depletion and increasing environmental pressure are one of the main challenges faced by the world today. Synthetic high-efficiency catalysts offer hope for efficient energy conversion and effective pollutant treatment. Single-atom catalysts (SACs) are promising candidates, utilizing atomic diffusion strategies for preparation. Different precursor diffusion forms include gas phase, solid phase, and liquid phase diffusion, with methods such as gas deposition, chemical vapor deposition, nanoparticle transformation, and electrochemical methods.

NANO RESEARCH (2021)

Article Chemistry, Physical

High-Loading Single-Atomic-Site Silver Catalysts with an Ag1-C2N1 Structure Showing Superior Performance for Epoxidation of Styrene

Shubo Tian et al.

Summary: A single-atomic-site Ag catalyst supported by mesoporous graphitic carbon nitride was developed for styrene epoxidation, demonstrating outstanding catalytic performance with high conversion (96%) and selectivity (81%). The catalyst with Ag-1-C2N1 structure showed higher activity and selectivity compared to analogous catalysts, attributed to absorbed superoxide-like O-2 species and lower reaction barrier for styrene oxide generation.

ACS CATALYSIS (2021)

Article Chemistry, Physical

Highly efficient conversion of methane to formic acid under mild conditions at ZSM-5-confined Fe-sites

Kaixin Zhu et al.

Summary: This study introduces a highly selective and efficient method for methane conversion to formic acid by confining atomically dispersed Fe sites in the nano-channels of ZSM-5. The research demonstrates that the confined Fe-O active centers within ZSM-5 can dissociate C-H bonds and catalyze the oxidation of methane to formic acid via free radical mechanisms under mild conditions. This innovative approach opens up a new path for engineering the microenvironment of confined Fe sites within nanochannels for highly selective methane conversion with low energy input.

NANO ENERGY (2021)

Article Chemistry, Applied

Copper-Catalyzed Selective N-Arylation of Oxadiazolones by Diaryliodonium Salts

Natalia S. Soldatova et al.

Summary: A method for copper-catalyzed N-arylation of diverse oxadiazolones using diaryliodonium salts has been reported with high yields up to 92%. It was found that the steric effects in aryl moieties determined the chemoselectivity of arylations. Mesityl-substituted diaryliodonium salts demonstrated high potential as selective arylation reagents.

ADVANCED SYNTHESIS & CATALYSIS (2021)

Article Engineering, Environmental

Molten-salt-assisted thermal emitting method to transform bulk Fe2O3 into Fe single atom catalysts for oxygen reduction reaction in Zn-air battery

Yuanjie Cao et al.

Summary: The efficient and low-cost electrocatalyst is developed by a molten-salt-assisted thermal emitting approach, which transforms cheap metal oxide powder into highly efficient single-atom catalyst for oxygen reduction reaction. The catalyst shows excellent performance and energy efficiency in alkaline media, outperforming precious metal catalysts.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Materials Science, Multidisciplinary

Biocatalysts at atom level: From coordination structure to medical applications

Yunguang Zhang et al.

Summary: Natural enzymes have limitations in biomedical engineering due to high cost, environmental sensitivity, and low production. Artificial enzymes like single-atom catalysts (SACs) have been proposed to replace natural enzymes, offering unique coordination structures and high catalytic activities. Fe, Co, Mn, Ni, and Cu SACs show promising enzyme-like properties and potential biological applications in biosensors and disease treatment, attracting interest in artificial enzyme research and nanomedicine.

APPLIED MATERIALS TODAY (2021)

Article Chemistry, Applied

Reaction kinetics and phase behavior in the chemoselective hydrogenation of 3-nitrostyrene over Co-N-C single-atom catalyst in compressed CO2

Dan Zhou et al.

Summary: This study reports the chemoselective hydrogenation of 3-nitrostyrene over noble-metal-free Co-N-C SAC in compressed CO2 as a green solvent for the first time. An interesting inverted V-curve relation is observed between the catalytic activity and CO2 pressure, with a phase behavior study revealing the formation of a bi-phase under certain conditions which significantly affects the reaction kinetics of the catalytic system.

CHINESE JOURNAL OF CATALYSIS (2021)

Article Chemistry, Physical

Molecular engineered palladium single atom catalysts with an M-C1N3 subunit for Suzuki coupling

Jia Liu et al.

Summary: Single atom catalysis is a powerful technique for catalysis, but the unpredictable nature of the single atom environment due to pyrolysis process affects its performance. Through a molecular engineering approach, Pd-N3C1-SAC with a pre-defined coordinating environment shows higher activity and efficiency compared to traditional SACs.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Physical

Recent advances in single-atom electrocatalysts supported on two-dimensional materials for the oxygen evolution reaction

Yanan Zhou et al.

Summary: The oxygen evolution reaction (OER) is a major bottleneck in the electrolytic water-splitting for hydrogen generation due to its sluggish kinetics. Constructing single-atom catalysts (SACs) on two-dimensional materials has become an important research direction to enhance OER performance.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Electrocatalysis for CO2 conversion: from fundamentals to value-added products

Genxiang Wang et al.

Summary: This article provides a comprehensive review of recent research progress on the selective electrocatalytic conversion of CO2 into value-added products. It covers the history and fundamental science of electrocatalytic CO2RR, the design, preparation, and performance evaluation of electrocatalysts, factors influencing the CO2RR, and associated theoretical calculations. Emphasis is placed on emerging trends in selective electrocatalytic conversion of CO2 and discussions on structure-performance relationships and mechanisms.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Multidisciplinary

Tandem catalyzing the hydrodeoxygenation of 5-hydroxymethylfurfural over a Ni3Fe intermetallic supported Pt single-atom site catalyst

Ge Meng et al.

Summary: A single-atom site catalyst (SAC) with dual reactive sites of isolated Pt single atoms and the Ni3Fe intermetallic support (Pt-1/Ni3Fe IMC) was reported for tandem catalysis of the hydrodeoxygenation of 5-hydroxymethylfurfural (5-HMF), exhibiting high catalytic performance at a low reaction temperature. Experimental and computational studies confirmed that Pt-1/Ni3Fe IMC can facilitate the hydrodeoxygenation reaction through a tandem mechanism.

CHEMICAL SCIENCE (2021)

Article Chemistry, Physical

Anti-sintering Au nanoparticles stabilized by a Fe-incorporated MgAl2O4 spinel for CO oxidation

Palle Ramana Murthy et al.

Summary: The study investigates the influence of lattice spacing of spinel support on thermal stability of immobilized gold nanoparticles, finding significant enhancement in stability of gold nanoparticles on MAFO compared to MAO at high temperatures, which helps preserve their catalytic activity towards CO oxidation. Additionally, the presence of water in the reaction stream was found to have a promotional effect on catalytic activity of gold nanocatalysts.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Review Chemistry, Multidisciplinary

Non-carbon-supported single-atom site catalysts for electrocatalysis

Xiaobo Zheng et al.

Summary: This review comprehensively summarizes the recent exciting progress on non-carbon-supported SACs and their applications in electrocatalytic reactions. Eight types of non-carbon-supported SACs are categorized to show their diversity, with detailed analysis of the anchoring and stabilization mechanisms. Advanced characterization techniques for identifying and monitoring the atomic structure of SACs are highlighted, along with discussions on their applications in electrochemical energy conversion.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms

Leilei Zhang et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Applied

One-pot assembling of hierarchical porous carbon/silica nanocomposites for cycloaddition reaction

Zhengjian Zhu et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2020)

Article Engineering, Chemical

Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran over Atomically Dispersed Ruthenium Catalysts

Yifei Liu et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

Article Chemistry, Multidisciplinary

Prospects of Heterogeneous Hydroformylation with Supported Single Atom Catalysts

Jonas Amsler et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Multidisciplinary Sciences

U1 snRNP regulates cancer cell migration and invasion in vitro

Jung-Min Oh et al.

NATURE COMMUNICATIONS (2020)

Review Physics, Multidisciplinary

Graphitic carbon nitride based single-atom photocatalysts

Junwei Fu et al.

FRONTIERS OF PHYSICS (2020)

Article Nanoscience & Nanotechnology

Hierarchically Porous Carbons Derived from Nonporous Coordination Polymers

Lei Tong et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Physical

High selective catalyst for ethylene epoxidation to ethylene oxide: A DFT investigation

Sarawoot Impeng et al.

APPLIED SURFACE SCIENCE (2020)

Review Chemistry, Multidisciplinary

Metal-Organic Framework-Based Catalysts with Single Metal Sites

Yong-Sheng Wei et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Multidisciplinary

Chemical Synthesis of Single Atomic Site Catalysts

Shufang Ji et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Multidisciplinary

Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications

Chao Gao et al.

CHEMICAL REVIEWS (2020)

Article Materials Science, Multidisciplinary

High-loading and thermally stable Pt1/MgAl1.2Fe0.8O4 single-atom catalysts for high-temperature applications

Kaipeng Liu et al.

SCIENCE CHINA-MATERIALS (2020)

Review Chemistry, Multidisciplinary

Surface Coordination Chemistry of Atomically Dispersed Metal Catalysts

Ruixuan Qin et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Inorganic & Nuclear

Metal-organic framework (MOF)-derived catalysts for fine chemical production

Hannelore Konnerth et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Article Chemistry, Multidisciplinary

Cation-Exchange Induced Precise Regulation of Single Copper Site Triggers Room-Temperature Oxidation of Benzene

Huang Zhou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Materials Science, Multidisciplinary

Single atom is not alone: Metal-support interactions in single-atom catalysis

Kun Qi et al.

MATERIALS TODAY (2020)

Review Chemistry, Physical

Recent Advances in MOF-Derived Single Atom Catalysts for Electrochemical Applications

Zhongxin Song et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Multidisciplinary

Isolated Single Atoms Anchored on N-Doped Carbon Materials as a Highly Efficient Catalyst for Electrochemical and Organic Reactions

Jian-Fei Sun et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Engineering, Chemical

The assembling principle and strategies of high-density atomically dispersed catalysts

Shuyan Zhao et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Chemistry, Applied

Hollow mesoporous CeO2 microspheres for efficient loading of Au single-atoms to catalyze the water-gas shift reaction

Yapeng Xiang et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2020)

Review Chemistry, Multidisciplinary

Single-Atom Catalysts Based on the Metal-Oxide Interaction

Rui Lang et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Multidisciplinary

Advanced Electrocatalysts with Single-Metal-Atom Active Sites

Yuxuan Wang et al.

CHEMICAL REVIEWS (2020)

Review Materials Science, Multidisciplinary

Recent Progress of Carbon-Supported Single-Atom Catalysts for Energy Conversion and Storage

Yongchao Yang et al.

MATTER (2020)

Review Chemistry, Multidisciplinary

Electronic Metal-Support Interaction of Single-Atom Catalysts and Applications in Electrocatalysis

Jiarui Yang et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Multidisciplinary

Mechanochemical Kilogram-Scale Synthesis of Noble Metal Single-Atom Catalysts

Xiaohui He et al.

CELL REPORTS PHYSICAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

From metal-organic frameworks to single/dual-atom and cluster metal catalysts for energy applications

Chun-Chao Hou et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity

Mi Yoo et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Catalytic reduction of CO2into fuels and fine chemicals

Arindam Modak et al.

GREEN CHEMISTRY (2020)

Review Chemistry, Physical

Recent advances in synergistic effect promoted catalysts for preferential oxidation of carbon monoxide

Peng Jing et al.

CATALYSIS SCIENCE & TECHNOLOGY (2020)

Review Engineering, Environmental

Design and application of heterogeneous catalysts as peroxydisulfate activator for organics removal: An overview

Wen-Da Oh et al.

CHEMICAL ENGINEERING JOURNAL (2019)

Article Chemistry, Multidisciplinary

Thermal Emitting Strategy to Synthesize Atomically Dispersed Pt Metal Sites from Bulk Pt Metal

Yunteng Qu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Physical

Catalytic hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to biofuel 2, 5-dimethylfuran

Xiaofeng Wang et al.

APPLIED CATALYSIS A-GENERAL (2019)

Review Chemistry, Multidisciplinary

Direct Methane Conversion under Mild Condition by Thermo-, Electro-, or Photocatalysis

Xianguang Meng et al.

Article Chemistry, Multidisciplinary

Liberating N-CNTs Confined Highly Dispersed Co-Nx Sites for Selective Hydrogenation of Quinolines

Wanbing Gong et al.

ADVANCED MATERIALS (2019)

Article Chemistry, Multidisciplinary

Pocketlike Active Site of Rh1/MoS2 Single-Atom Catalyst for Selective Crotonaldehyde Hydrogenation

Yang Lou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Recent Developments in Heterogeneous Catalyzed Epoxidation of Styrene to Styrene Oxide

Manohar Singh Batra et al.

CHEMISTRYSELECT (2019)

Article Multidisciplinary Sciences

Double-slit photoelectron interference in strong-field ionization of the neon dimer

Maksim Kunitski et al.

NATURE COMMUNICATIONS (2019)

Review Chemistry, Inorganic & Nuclear

Current progress of metallic and carbon-based nanostructure catalysts towards the electrochemical reduction of CO2

Liang Hou et al.

INORGANIC CHEMISTRY FRONTIERS (2019)

Review Chemistry, Applied

Recent advances in heterogeneous catalytic hydrogenation and dehydrogenation of N-heterocycles

Zhongzhe Wei et al.

CHINESE JOURNAL OF CATALYSIS (2019)

Article Chemistry, Multidisciplinary

Metalloporphyrin Polymers with Intercalated Ionic Liquids for Synergistic CO2 Fixation via Cyclic Carbonate Production

Yaju Chen et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Article Chemistry, Multidisciplinary

Single Pt Atoms Confined into a Metal-Organic Framework for Efficient Photocatalysis

Xinzuo Fang et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Multidisciplinary

Selective Hydrogenation of CO2 to Ethanol over Cobalt Catalysts

Lingxiang Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Multidisciplinary

Iridium-based hydride transfer catalysts: from hydrogen storage to fine chemicals

Zhiyao Lu et al.

CHEMICAL COMMUNICATIONS (2018)

Review Chemistry, Multidisciplinary

Catalytic oxidation of carbohydrates into organic acids and furan chemicals

Zehui Zhang et al.

CHEMICAL SOCIETY REVIEWS (2018)

Review Chemistry, Inorganic & Nuclear

Coordination polymers and metal-organic frameworks built up with poly(tetrazolate) ligands

Aurel Tabacaru et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Article Nanoscience & Nanotechnology

A heterogeneous single-atom palladium catalyst surpassing homogeneous systems for Suzuki coupling

Zupeng Chen et al.

NATURE NANOTECHNOLOGY (2018)

Article Nanoscience & Nanotechnology

Direct observation of noble metal nanoparticles transforming to thermally stable single atoms

Shengjie Wei et al.

NATURE NANOTECHNOLOGY (2018)

Article Multidisciplinary Sciences

Structural absorption by barbule microstructures of super black bird of paradise feathers

Dakota E. McCoy et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Physical

Electrochemical CO2 Reduction with Atomic Iron-Dispersed on Nitrogen-Doped Graphene

Chenhao Zhang et al.

ADVANCED ENERGY MATERIALS (2018)

Article Chemistry, Multidisciplinary

Room-Temperature Methane Conversion by Graphene-Confined Single Iron Atoms

Xiaoju Cui et al.

Review Chemistry, Multidisciplinary

Heterogeneous single-atom catalysis

Aiqin Wang et al.

NATURE REVIEWS CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

InSitu Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts

Jian Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Multidisciplinary Sciences

Single-atom catalyst: a rising star for green synthesis of fine chemicals

Leilei Zhang et al.

NATIONAL SCIENCE REVIEW (2018)

Article Chemistry, Multidisciplinary

Fabrication of Single-Atom Catalysts with Precise Structure and High Metal Loading

Jing Wang et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Multidisciplinary

Reaction Mechanisms of Well-Defined Metal-N-4 Sites in Electrocatalytic CO2 Reduction

Zheng Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Multidisciplinary Sciences

Light-driven fine chemical production in yeast biohybrids

Junling Guo et al.

SCIENCE (2018)

Article Chemistry, Physical

An atomic-scale view of single-site Pt catalysis for low-temperature CO oxidation

Andrew J. Therrien et al.

NATURE CATALYSIS (2018)

Article Chemistry, Applied

Hierarchical OD/2D Co3O4 hybrids rich in oxygen vacancies as catalysts towards styrene epoxidation reaction

Jiangyong Liu et al.

CHINESE JOURNAL OF CATALYSIS (2018)

Article Chemistry, Multidisciplinary

Selective Activation of Methane on Single-Atom Catalyst of Rhodium Dispersed on Zirconia for Direct Conversion

Yongwoo Kwon et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Chemistry, Physical

Design Strategies toward Advanced MOF-Derived Electrocatalysts for Energy-Conversion Reactions

Jinlong Liu et al.

ADVANCED ENERGY MATERIALS (2017)

Review Chemistry, Physical

A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons

Haiyan Yang et al.

CATALYSIS SCIENCE & TECHNOLOGY (2017)

Review Materials Science, Multidisciplinary

Fluorine-functionalized metal-organic frameworks and porous coordination polymers

Shin-ichiro Noro et al.

NPG ASIA MATERIALS (2017)

Article Multidisciplinary Sciences

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping

John Jones et al.

SCIENCE (2016)

Article Chemistry, Multidisciplinary

Mechanochemical synthesis of advanced nanomaterials for catalytic applications

Chunping Xu et al.

CHEMICAL COMMUNICATIONS (2015)

Review Chemistry, Multidisciplinary

Metal-organic frameworks and their derived nanostructures for electrochemical energy storage and conversion

Wei Xia et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

Article Multidisciplinary Sciences

Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen

Xiaoguang Guo et al.

SCIENCE (2014)

Article Chemistry, Multidisciplinary

Heterogenized cobalt oxide catalysts for nitroarene reduction by pyrolysis of molecularly defined complexes

Felix A. Westerhaus et al.

NATURE CHEMISTRY (2013)

Review Multidisciplinary Sciences

The Chemistry and Applications of Metal-Organic Frameworks

Hiroyasu Furukawa et al.

SCIENCE (2013)

Review Chemistry, Multidisciplinary

Mechanochemistry: opportunities for new and cleaner synthesis

Stuart L. James et al.

CHEMICAL SOCIETY REVIEWS (2012)

Article Multidisciplinary Sciences

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations

Georgios Kyriakou et al.

SCIENCE (2012)

Article Chemistry, Multidisciplinary

Size effect of graphene on electrocatalytic activation of oxygen

Dehui Deng et al.

CHEMICAL COMMUNICATIONS (2011)

Article Chemistry, Multidisciplinary

Single-atom catalysis of CO oxidation using Pt1/FeOx

Botao Qiao et al.

NATURE CHEMISTRY (2011)

Review Chemistry, Multidisciplinary

The teraton challenge. A review of fixation and transformation of carbon dioxide

Mette Mikkelsen et al.

ENERGY & ENVIRONMENTAL SCIENCE (2010)

Review Chemistry, Multidisciplinary

Ligands for practical rhodium-catalyzed asymmetric hydroformylation

Jerzy Klosin et al.

ACCOUNTS OF CHEMICAL RESEARCH (2007)

Article Multidisciplinary Sciences

A one-step conversion of benzene to phenol with a palladium membrane

S Niwa et al.

SCIENCE (2002)