4.7 Article

Calix[n]triazolium based turn-on fluorescent sensing ensemble for selective adenosine monophosphate (AMP) detection

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CHEMICAL COMMUNICATIONS
卷 57, 期 91, 页码 12139-12142

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04950j

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A novel calix[n]triazolium was synthesized, which showed excellent selectivity for detecting AMP through turn-on fluorescence. This macrocyclic system is the first to discriminate AMP from ADP and ATP based on fluorescence changes.
A novel calix[n]triazolium was synthesized and exhibited excellent selectivity for AMP. The binding between calix[n]triazolium and chromenolate anions forms a non-fluorescent complex and the resulting supramolecular ensemble selectively detects AMP in water and induces turn-on fluorescence. The sensing platform is the first macrocyclic system to discriminate AMP from ADP and ATP through fluorescence changes.

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