High nuclearity structurally - related Mn supertetrahedral T4 aggregates

The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn-24] and [Mn-23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

Automated summary

Simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has led to the synthesis of three new, structurally-related [Mn-24] and [Mn-23] clusters, based on nanosized supertetrahedal T4 Mn/O structural cores exhibiting slow relaxation of magnetization below 3.5 K.