Antiferromagnetic resonance in the cubic iridium hexahalides (NH4)2IrCl6 and K2IrCl6

We report on high-field electron spin resonance studies of two iridium hexahalide compounds (NH4)(2)IrCl6 and K2IrCl6. In the paramagnetic state, our measurements reveal isotropic g factors g = 1.79(1) for the Ir4+ ions, in agreement with their cubic symmetries. Most importantly, in the magnetically ordered state, we observe two magnon modes with zero-field gaps of 11.3 and 14.2 K for (NH4)(2)IrCl6 and K2IrCl6, respectively. Based on that and using linear spin-wave theory, we estimate the nearest-neighbor exchange couplings and anisotropic Kitaev interactions J(1)/k(B) = 10.3 K, K/k(B) = 0.7 K for (NH4)(2)IrCl6, and J(1)/k(B) = 13.8 K, K/k(B) = 0.9 K for K2IrCl6, revealing the nearest-neighbor Heisenberg coupling as the leading interaction term, with only a weak Kitaev anisotropy.

Automated summary

This study reports high-field electron spin resonance studies of two iridium hexahalide compounds, revealing different magnon modes and estimated exchange couplings and anisotropic Kitaev interactions in the magnetically ordered state. The nearest-neighbor Heisenberg coupling was identified as the leading interaction term with weak Kitaev anisotropy.