期刊
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
卷 9, 期 5, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2021.106230
关键词
NH2-MIL-125(Ti); Microwave-assisted synthesis; Photocatalysis; Water treatment; Emerging pollutants
资金
- Spanish Ministry of Science, Innovation and Universities
- Juan de la Cierva Formaci 'on program [FJC2018-035513-I]
- State Research Agency (Spain) [PID2019-106186RB-I00/AEI/10.13039/501100011033]
NH2-MIL-125(Ti) MOFs were prepared by microwave-assisted synthesis under different conditions and used as photocatalysts for the breakdown of pharmaceuticals in water. The MOF prepared at 200 degrees C under 15 min microwave radiation exhibited the best crystalline structure and porosity, with good visible light absorption properties, and showed the highest performance in the removal of diclofenac.
NH2-MIL-125(Ti) MOFs have been prepared by microwave-assisted synthesis under different conditions of temperature (140-200 degrees C) and holding time (15 min to 4 h). The resulting materials have been tested as photocatalysts for the breakdown of six pharmaceuticals in aqueous solution under solar simulated irradiation. A full characterization of the solid samples by X Ray Diffraction, N-2 adsorption-desorption, UV-visible DRS, and photoluminescence techniques was carried out. The MOF prepared at 200 degrees C under 15 min microwave radiation displayed the best-defined crystalline structure and most developed porosity (1030 m(2) g(-1) BET surface area and 0.45 cm(3) g(-1) pore volume), with good optical properties for visible light absorption (bandgap 2.59 eV). This photocatalyst showed the best performance in the removal of diclofenac (complete conversion in 3 h; pseudo-first order rate constant of 1.11 +/- 0.09 h(-1)) in batch tests. Further diclofenac photo-degradation experiments under continuous flow confirmed the high stability of the MOF with no loss of photocatalytic activity (10 h of time on stream). The degradation of a mixture of six other pharmaceutical compounds (acetaminophen, cipmfloxacin, tetracycline, sulfamethoxazole, diclofenac and ibuprofen) was also studied to learn more on the efficiency of the process against compounds of different chemical structure.
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