期刊
NANOSCALE
卷 13, 期 46, 页码 19453-19465出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nr02833b
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资金
- Department of Science and Technology [DST 1689]
- Ministry of Human Resource and Development
In this study, a three-dimensional carbon foam-based asymmetric planar micro-supercapacitor was fabricated, showing superior electrochemical performance and ultrahigh supercapacitance. This micro-supercapacitor achieved a high supercapacitance of 18.4 mF cm(-2) at a scan rate of 5 mV s(-1) and maintained 86.1% capacitance retention after 10,000 electrochemical cycles.
A three-dimensional carbon foam (CF)-based asymmetric planar micro-supercapacitor is fabricated by the direct spray patterning of active materials on an array of interdigital electrodes. The solid-state asymmetric micro-supercapacitor comprises the CF network with pseudocapacitive metal oxides (manganese oxide (MnO), iron oxide (Fe2O3)), where CF-MnO composite as a positive electrode, and CF-Fe2O3 as negative electrode for superior electrochemical performance. The micro-supercapacitor, CF-MnO//CF-Fe2O3, attains an ultrahigh supercapacitance of 18.4 mF cm(-2) (2326.8 mF cm(-3)) at a scan rate of 5 mV s(-1). A wider potential window of 1.4 V is achieved with a high energy density of 5 mu W h cm(-2). The excellent cyclic stability is confirmed by 86.1% capacitance retention after 10 000 electrochemical cycles.
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