期刊
出版社
BUREAU SCIENTIFIC PUBL
DOI: 10.17159/0379-4350/2021/v74a9
关键词
Pyrazolyl catalysts; sorbic acid; hydrogenation; selectivity
资金
- Royal Society-Department for International Development, United Kingdom (RS-DFID-UK) [207043]
The study prepared various complexes by reacting different pyrazole-based compounds with palladium and nickel compounds, which were then used as catalysts in the hydrogenation of sorbic acid. The active catalysts showed significant activities and selectivity in reducing sorbic acid, indicating a sequential hydrogenation process with preference for less hindered C=C bonds.
We have prepared several pyrazolyl palladium and nickel complexes ([(L1)PdCl2] (1), [(L2) PdCl2] (2), [(L3) PdCl2] (3), [(L1) NiBr2] (4), [(L2) NiBr2] (5) and [(L3) NiBr2] (6)) by reacting 3,5-dimethy1-1H-pyrazole (L1), 3,5-di-tert-butyl-1H-pyrazole (L2) and 5-ferrocenyl-1H-pyrazole(L3) with [PdCl2(NCMe)(2)] or [NiBr2(DME)] to afford mononuclear palladium and nickel complexes, respectively. These complexes were then investigated as pre-catalysts in the hydrogenation of 2,4-hexadienoic acid (sorbic acid). The active catalysts from these complexes demonstrate significant activities under mild experimental conditions. Additionally, the active catalysts show that the hydrogenation of sorbic acid proceeds in a sequential manner, where the less hindered C=C bond (4-hexenoic acid) is preferentially reduced over the more hindered C=C bond (2-hexenoic acid).
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