期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 19, 期 48, 页码 10472-10492出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ob01939b
关键词
-
资金
- Ministerio de Ciencia e Innovacion [CTQ2016-75023-C2-1-P, PID2020-115789GB-C21]
- FEDER [CTQ2016-75023-C2-1-P, PID2020-115789GB-C21, BU291P18, BU049P20]
- Junta de Castilla y Leon [BU291P18, BU049P20]
- la Caixa Foundation [LCF/PR/PR18/51130007>(CAIXA-UBU001)]
Dioxomolybdenum complexes have shown great potential in deoxygenation reactions of various compounds, including sulfoxides, N-O bonds, and nitro functional groups.
Dioxomolybdenum(vi) complexes have been applied as efficient, inexpensive and benign catalysts to deoxygenation reactions of a diverse number of compounds in the last two decades. Dioxomolybdenum complexes have demonstrated wide applicability to the deoxygenation of sulfoxides into sulfides and reduction of N-O bonds. Even the challenging nitro functional group was efficiently deoxygenated, affording amines or diverse heterocycles after reductive cyclization reactions. More recently, carbon-based substrates like epoxides, alcohols and ketones have been successfully deoxygenated. Also, dioxomolybdenum complexes accomplished deoxydehydration (DODH) reactions of biomass-derived vicinal 1,2-diols, affording valuable alkenes. The choice of the catalytic systems and reductant is decisive to achieve the desired transformation. Commonly found reducing agents involved phosphorous-based compounds, silanes, molecular hydrogen, or even glycols and other alcohols.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据