The Effect of a Receding Saline Lake (The Salton Sea) on Airborne Particulate Matter Composition

The composition of ambient particulate matter (PM) and its sources were investigated at the Salton Sea, a shrinking saline lake in California. To investigate the influence of playa exposure on PM composition, PM samples were collected during two seasons and at two sites around the Salton Sea. To characterize source composition, soil samples were collected from local playa and desert surfaces. PM and soil samples were analyzed for 15 elements using mass spectrometry and X-ray diffraction. The contribution of sources to PM mass and composition was investigated using Al-referenced enrichment factors (EFs) and source factors resolved from positive matrix factorization (PMF). Playa soils were found to be significantly enriched in Ca, Na, and Se relative to desert soils. PMF analysis resolved the PM10 data with four source factors, identified as Playa-like, Desert-like, Ca-rich, and Se. Playa-like and desert-like sources were estimated to contribute to a daily average of 8.9% and 45% of PMio mass, respectively. Additionally, playa sources were estimated to contribute to 38-68% of PM10 Na. PM10 Se concentrations showed strong seasonal variations, suggesting a seasonal cycle of Se volatilization and recondensation. These results support the importance of playas as a source of PM mass and a controlling factor of PM composition.