期刊
ENVIRONMENTAL SCIENCE & TECHNOLOGY
卷 51, 期 21, 页码 12998-13007出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.est.7b03308
关键词
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资金
- Ministry of Education of Singapore
- GSK Singapore
- NUS
- National Research Foundation (NRF), Prime Minister's Office of Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE)
Exploring efficient and low-cost solid sorbents is essential for carbon capture and storage. Herein, a novel class of high-performance CO2 adsorbent (rGO@MgO/C) is engineered based on the controllable integration of reduced graphene oxide (rGO), amorphous carbon, and MgO nanocrystallites. The optimized rGO@MgO/C nanocomposite exhibits remarkable CO2 capture capacity (up to 31.5 wt % at 27 degrees C, 1 bar CO2, and 22.5 wt % under the simulated flue gas), fast sorption rate, and strong process durability. The enhanced capture capability of CO2 is the best among all of the MgO-based sorbents reported so far. The high performance of rGO@MgO/C nanocomposite can be ascribed to the hierarchical architecture and special physicochemical features, including the sheet-on-sheet sandwich-like structure, ultrathin nanosheets with abundant nanopores, large surface area, and highly dispersed ultrafine MgO nanocrystallites (ca. 3 nm in size), together with the rGO sheets and in situ generated amorphous carbon that serve as a dual carbon support and protectant system with which to prevent MgO nanocrystallites from agglomeration. In addition, the CO2-uptake capacity at intermediate temperature (e.g., 350 degrees C) can be further improved threefold through alkali metal salt promotion treatment. This work provides a facile and effective strategy with which to engineer advanced graphene-based functional nanocomposites with rationally designed compositions and architectures for potential applications in the field of gas storage and separation.
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