4.4 Article

Conversion of furan derivatives for preparation of biofuels over Ni-Cu/C catalyst

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/15567036.2017.1310959

关键词

Biofuel; 2,5-dimethylfuran; furfural; hydrogen donor; 5-hydroxymethylfurfural; 2-methylfuran

资金

  1. National Natural Science Foundation of China [51476180]

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Conversions of furfural and 5-hydroxymethylfurfural as model components in bio-oil were investigated over Ni-Cu/C catalyst with formic acid as hydrogen donor in isopropanol solvent to produce biofuels. The effects of reaction temperature, feed ratio, and reaction time were studied. A high yield of 2-methylfuran up to 91 mol% was obtained from furfural in 8 h at 200 degrees C, and under same conditions 80 mol% yield of 2,5-dimethylfuran could also be obtained from 5-hydroxymethylfurfural in 6 h. The results verified the catalyst performance and the availability of the reaction conditions for producing biofuels from furan derivatives.

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