期刊
ENERGY CONVERSION AND MANAGEMENT
卷 149, 期 -, 页码 675-685出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.enconman.2017.07.059
关键词
Biomass; Polystyrene; Pyrolysis; TGA/MS/FT-IR; Kinetic; Gas analysis
资金
- TUBITAK through the BIDEB 2214-A
The purpose of this study was to investigate the effect on polystyrene (PS) during co-pyrolysis with biomass through thermal decomposition. The model-free iso-conversional methods (Kissinger, Friedman, Flynn-WallOzawa, Kissinger-Akahira-Sunose, Starink and Vyazovkin) were adopted to calculate activation energy of the pyrolysis and co-pyrolysis process of two biomass samples (walnut shell: WS and peach stones: PST) with PS. It is found that biomass blending to PS decreased activation energy values and resulted in multi-step reaction mechanisms. Furthermore, changes in the evolution profiles of methyl, water, methoxy, carbon dioxide, benzene and styrene was monitored through evolved gas analysis via TGA/FT-IR and TGA/MS. Detection of temperature dependent release of volatiles indicated the differences occur as a result of compositional differences of biomass.
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