4.7 Article

Reforming of Poly(3-hydroxybutyrate) to High-Quality Oil with Acidic Phosphates

期刊

ENERGY & FUELS
卷 31, 期 10, 页码 11211-11216

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AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.7b01517

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资金

  1. National Natural Science Foundation of China [21606045]

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Poly(3-hydroxybutyrate) (PHB) derived from renewable biological feedstocks is regarded as a potential material for high-quality oil production through weak acid catalysis. PHB can be converted to PHB oil in a single-step reaction catalyzed by aluminum dihydrogen phosphate, and the yield can reach 36.9 wt % at mild reaction conditions (240 degrees C for 6 h). The hydrogen/carbon ratio and higher heating value of the oil obtained are 1.63 and 42.3 MJ/kg, respectively, which makes it comparable to that of oxygenated commercial gasoline.

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