期刊
INORGANIC AND NANO-METAL CHEMISTRY
卷 47, 期 2, 页码 202-212出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/15533174.2015.1137589
关键词
Dithiocarbamates; crystal structures; metal sulfides; chalcogenides; nanoparticles
资金
- GMRDC, University of Fort Hare, South Africa
- School of Chemistry, University of KwaZulu-Natal Westville Campus
Zn(II), Cd(II), and Hg(II) dithiocarbamate complexes were synthesize and characterized by elemental analysis, thermogravimetric analysis, UV-Vis, FTIR, and H-1-and C-13-NMR spectroscopy. Single-crystal X-ray crystallography revealed that the Zn complex has a centrosymmetric dimeric structure while the Hg complex crystallizes with two monomeric molecules of the mercury complex and two molecules of toluene solvent in the asymmetric unit. The compounds were used as single molecule precursors to synthesize HDA capped metal sulfides nanoparticles with average crystallite size ranging from 7 to 22 nm. The optical properties of the nanoparticles showed evidence of quantum confinement.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据