A Poriferous Nanoflake-Assembled Flower-Like Ni5P4 Anode for High-Performance Sodium-Ion Batteries

Sodium-ion batteries (SIBs) have been regarded as one of the most competitive alternatives for lithium-ion batteries (LIBs) due to the abundance of sodium and comparable electrochemical characteristics of sodium to that of lithium. However, while highly desired, developing stable anode materials remains a critical challenge. In this work, the development of a stable anode for SIBs is reported, a poriferous nanoflake-assembled flower-like nickel tetraphosphide (PNAF-NP) with high surface area and typical mesoporous property. Due to the unique structure, the PANF-NP anode exhibits excellent reversible capacity of 648.34mAhg(-1) at 0.2Ag(-1) with a Coulombic efficiency of 98.67%, and superior cycling stability at 0.2Ag(-1) with high retention capacity of 456.34 mAhg(-1) and average Coulombic efficiency of 99.19% after 300 cycles. Moreover, the high reversible capacity of 614.43, 589.49, 512.66, and 432.23mAhg(-1) is achieved at 0.5, 1, 2, and 5Ag(-1), respectively, indicating the superior rate capability of the PNAF-NP anode. This work represents a great advancement in the field of SIBs by reporting a high-performance anode material.

Automated summary

In this study, a stable anode material for SIBs, porous nanoflake-assembled flower-like nickel tetraphosphide (PNAF-NP) with high surface area and mesoporous property, was developed. The PNAF-NP anode exhibited excellent reversible capacity and cycling stability at various discharge rates, demonstrating superior rate capability. This work represents a significant advancement in the field of SIBs by introducing a high-performance anode material.