An unusual self-assembling columnar mesogen prepared by tethering a planar naphthalenediimide acceptor to bent phenothiazine donors

We describe a synthetic approach to achieving columnar stacked mesogens of aromatic electron donors (D) and acceptors (A) as an orthogonal strategy to segregate charge carrying channels in films. An unusual columnar liquid crystalline mesogen was designed, such that a planar naphthalenediimide acceptor flanked by two bent-shaped phenothiazine donor moieties self-assembled into a liquid crystalline phase. The use of different shapes in the D-A-D arrangement could allow segregated charge transport columns, thus limiting both intercolumnar and intramolecular D-A interactions. In solution, the mesogen showed independent optical and electronic properties of its constituent D and A components and annealed films of the columnar liquid crystalline material showed a near doubling of photocurrent generation compared to amorphousfilms.

Automated summary

The study describes a synthetic approach to achieving columnar stacked mesogens of aromatic electron donors and acceptors, which can segregate charge transport channels in films. The use of different shapes in the D-A-D arrangement limits D-A interactions and leads to an increased photocurrent generation rate compared to amorphous films.