期刊
JACS AU
卷 2, 期 2, 页码 261-279出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacsau.1c00129
关键词
organofluorine compounds; organoboron reagents; fluorinated organoboron compounds
资金
- National Natural Science Foundation [21772046, 2193103]
This review provides guidance on the research of fluorinated organoboron compounds, focusing on selective monodefluoro-borylation of polyfluoroarenes and polyfluoroalkenes, selective borylation of fluorinated substrates, selective fluorination of organoboron compounds, and borofluorination of alkynes/olefins.
Fluorinated organoboron compounds are important synthetic building blocks that combine the unique characteristics of a fluorinated motif with the versatile synthetic applications of organoboron moiety. This review article guides the research on fluorinated organoboron compounds mainly from four aspects in recent years: selective monodefluoro-borylation of polyfluoroarenes and polyfluoroalkenes, selective borylation of fluorinated substrates, selective fluorination of organoboron compounds, and borofluorination of alkynes/olefins. In addition, this review will provide a necessary guidance and inspiration for the research on the valuable synthetic building block fluorinated organoboron compounds.
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