Sandwich-like chitosan porous carbon Spheres/MXene composite with high specific capacitance and rate performance for supercapacitors

The application of porous carbon microspheres derived from pure biomass in supercapacitors is restricted due to their limited reactive groups. MXene owns a combination of redox Faradic surface with good metallic conductivity and hydrophilicity, which assists to obtain high pseudocapaci-tance and energy density. Herein, Ti3C2TxMXene was introduced to chitosan-based porous carbon microsphere (CPCM) to fabricated sandwich-like structure (CPCM/MXene) through electrostatic interaction. The Ti3C2T x protected the spherical structure of CPCM. Meanwhile, CPCM hindered the reaggregation of Ti3C2T x by inserting in the Ti3C2T x layers, promoting the electrolyte migra-tion kinetics. The synergistic effect endowed CPCM/MXene high specific capacitance of 362 F/g at current density of 0.5 A/g and acceptable cycling stability with 93.87% capacitance retention at a high current density of 10 A/g after 10,000 cycles. Furthermore, CPCM/MXene displayed a high energy density of 27.8 W/(h center dot kg) at 500.0 W/kg of power density. These satisfactory perfor-mances prove that combining Ti3C2T x MXene nanosheets with porous carbon microspheres is a considering method to construct a new generation electrode material of supercapacitor.

Automated summary

This study combines Ti3C2Tx MXene nanosheets with porous carbon microspheres to construct a sandwich-like structure, which exhibits high specific capacitance and good cycling stability in supercapacitors.