4.2 Article

Co-assembling system that exhibits bright circularly polarized luminescence

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MATERIALS ADVANCES
卷 3, 期 7, 页码 -

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ma00002d

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资金

  1. Japan Society for the Promotion of Science (JSPS) [20K05283, 19K15376]
  2. Supporting Program for Interaction-based Initiative Team Studies (SPIRITS) 2020 of Kyoto University
  3. France-Japan International Associated Laboratory, Chiral Nanostructures for Photonic Applications (LIA-CNPA) from the Centre National de la Recherche Scientifique (CNRS)
  4. Universite de Bordeaux
  5. Grants-in-Aid for Scientific Research [19K15376, 20K05283] Funding Source: KAKEN

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The study demonstrates a co-assembling system that exhibits circularly polarized luminescence with a high dissymmetry factor and strong emission. This could potentially lead to the development of light-sensitive molecules with practical applications.
We demonstrate that a co-assembling system comprising a nonchiral cyanine dye and an enantiomeric lysine-derived amphiphile assembly show circularly polarized luminescence with a high dissymmetry factor (|g(lum)| = 0.14) in combination with strong emission (quantum yield phi = 0.70, absorption coefficient epsilon = 3.7 x 10(5) M-1 cm(-1)). The circular polarization luminosity of the main transition band was calculated as 4.9 x 10(-2).

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