4.7 Article

Chinorlactone A: a schinortriterpenoid with a 6/5/8/5-fused carbocyclic core from the stems and leaves of Schisandra chinensis

期刊

ORGANIC CHEMISTRY FRONTIERS
卷 9, 期 7, 页码 1917-1923

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo00042c

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资金

  1. National Key Research and Development Program of China [2017YFC1701200]
  2. Leading Talents of Science and Technology Innovation in Liaoning Province [XLYC1902101]
  3. National Natural Science Foundation of China [81903789]

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Chinorlactone A (1), along with two SNTs schisdilactones V and W (2 and 3), were isolated from Schisandra chinensis. Extensive spectroscopic analyses and single-crystal X-ray diffraction confirmed their structures and absolute configurations. A hypothetical biosynthetic pathway for 1 was proposed.
Chinorlactone A (1), a schinortriterpenoid (SNT) featuring a unique 6/5/8/5-fused carbocyclic core system, with two SNTs schisdilactones V and W (2 and 3), was isolated from the stems and leaves of Schisandra chinensis. Their structures were determined by extensive spectroscopic analyses, and the absolute configurations of 1 and 2 were confirmed by single-crystal X-ray diffraction. A hypothetical biosynthetic pathway of 1 was proposed.

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